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Synthesis of a Novel L-Tartaric Acid Derived Homochiral Nanoscale Framework and Its Application in L-Proline Detection and Acetalization Catalysis

Received: 29 November 2014     Accepted: 19 December 2014     Published: 3 January 2015
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Abstract

A novel homochiral nanoscale compound, [Ca(L-C4H4O6)(H2O)2]•2H2O (Ca(L-tart)(H2O)2), which is derived from calcium ions and L-tartaric acid (L-tart =C4H4O6), was synthesized under hydrothermal condition. It has been characterized by single crystal X-ray diffraction, SEM, XRD, FTIR and TG. The calcium atoms adopt a tetrahedron geometry and each atom coordinates with eight oxygen atoms. The compound forms a two-dimensional network structure in the solid state via hydrogen bonds. Its performance of L-proline detection was tested, which attained effective result for the porous framework. Meanwhile, the high activity was also shown in acetalization catalysis.

Published in American Journal of Nano Research and Applications (Volume 3, Issue 1-1)

This article belongs to the Special Issue Nanomaterials and Nanosensors for Chemical and Biological Detection

DOI 10.11648/j.nano.s.2015030101.12
Page(s) 8-12
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2015. Published by Science Publishing Group

Keywords

L-Tartaric Acid, Inorganic-Organic Framework Compound, L-Proline Detection

References
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Cite This Article
  • APA Style

    Xiong Peng, Radoelizo S. A., Liping Liu, Yi Luan. (2015). Synthesis of a Novel L-Tartaric Acid Derived Homochiral Nanoscale Framework and Its Application in L-Proline Detection and Acetalization Catalysis. American Journal of Nano Research and Applications, 3(1-1), 8-12. https://doi.org/10.11648/j.nano.s.2015030101.12

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    ACS Style

    Xiong Peng; Radoelizo S. A.; Liping Liu; Yi Luan. Synthesis of a Novel L-Tartaric Acid Derived Homochiral Nanoscale Framework and Its Application in L-Proline Detection and Acetalization Catalysis. Am. J. Nano Res. Appl. 2015, 3(1-1), 8-12. doi: 10.11648/j.nano.s.2015030101.12

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    AMA Style

    Xiong Peng, Radoelizo S. A., Liping Liu, Yi Luan. Synthesis of a Novel L-Tartaric Acid Derived Homochiral Nanoscale Framework and Its Application in L-Proline Detection and Acetalization Catalysis. Am J Nano Res Appl. 2015;3(1-1):8-12. doi: 10.11648/j.nano.s.2015030101.12

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  • @article{10.11648/j.nano.s.2015030101.12,
      author = {Xiong Peng and Radoelizo S. A. and Liping Liu and Yi Luan},
      title = {Synthesis of a Novel L-Tartaric Acid Derived Homochiral Nanoscale Framework and Its Application in L-Proline Detection and Acetalization Catalysis},
      journal = {American Journal of Nano Research and Applications},
      volume = {3},
      number = {1-1},
      pages = {8-12},
      doi = {10.11648/j.nano.s.2015030101.12},
      url = {https://doi.org/10.11648/j.nano.s.2015030101.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.nano.s.2015030101.12},
      abstract = {A novel homochiral nanoscale compound, [Ca(L-C4H4O6)(H2O)2]•2H2O (Ca(L-tart)(H2O)2), which is derived from calcium ions and L-tartaric acid (L-tart =C4H4O6), was synthesized under hydrothermal condition. It has been characterized by single crystal X-ray diffraction, SEM, XRD, FTIR and TG. The calcium atoms adopt a tetrahedron geometry and each atom coordinates with eight oxygen atoms. The compound forms a two-dimensional network structure in the solid state via hydrogen bonds. Its performance of L-proline detection was tested, which attained effective result for the porous framework. Meanwhile, the high activity was also shown in acetalization catalysis.},
     year = {2015}
    }
    

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  • TY  - JOUR
    T1  - Synthesis of a Novel L-Tartaric Acid Derived Homochiral Nanoscale Framework and Its Application in L-Proline Detection and Acetalization Catalysis
    AU  - Xiong Peng
    AU  - Radoelizo S. A.
    AU  - Liping Liu
    AU  - Yi Luan
    Y1  - 2015/01/03
    PY  - 2015
    N1  - https://doi.org/10.11648/j.nano.s.2015030101.12
    DO  - 10.11648/j.nano.s.2015030101.12
    T2  - American Journal of Nano Research and Applications
    JF  - American Journal of Nano Research and Applications
    JO  - American Journal of Nano Research and Applications
    SP  - 8
    EP  - 12
    PB  - Science Publishing Group
    SN  - 2575-3738
    UR  - https://doi.org/10.11648/j.nano.s.2015030101.12
    AB  - A novel homochiral nanoscale compound, [Ca(L-C4H4O6)(H2O)2]•2H2O (Ca(L-tart)(H2O)2), which is derived from calcium ions and L-tartaric acid (L-tart =C4H4O6), was synthesized under hydrothermal condition. It has been characterized by single crystal X-ray diffraction, SEM, XRD, FTIR and TG. The calcium atoms adopt a tetrahedron geometry and each atom coordinates with eight oxygen atoms. The compound forms a two-dimensional network structure in the solid state via hydrogen bonds. Its performance of L-proline detection was tested, which attained effective result for the porous framework. Meanwhile, the high activity was also shown in acetalization catalysis.
    VL  - 3
    IS  - 1-1
    ER  - 

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Author Information
  • School of Materials Science and Engineering, University of Science and Technology Beijing, 30 Xueyuan Road, Haidian district, Beijing, 100083 (P. R. China)

  • School of Materials Science and Engineering, University of Science and Technology Beijing, 30 Xueyuan Road, Haidian district, Beijing, 100083 (P. R. China)

  • School of Materials Science and Engineering, University of Science and Technology Beijing, 30 Xueyuan Road, Haidian district, Beijing, 100083 (P. R. China)

  • School of Materials Science and Engineering, University of Science and Technology Beijing, 30 Xueyuan Road, Haidian district, Beijing, 100083 (P. R. China)

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